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The Heptacyanotungstate(IV) Anion: A New 5 d Transition-Metal Member of the Rare Heptacyanometallate Family of Anions.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2016 Sep 12; Vol. 55 (38), pp. 11368-71. Date of Electronic Publication: 2016 Jun 30. - Publication Year :
- 2016
-
Abstract
- The heptacyanotungstate(IV) anion was isolated in the salt (n-Bu4 N)3 [W(IV) (CN)7 ] (1) from the reduction of (n-Bu4 N)3 [W(V) (CN)8 ] with concomitant loss of one cyanide ligand. The anion in 1 adopts a slightly distorted pentagonal bipyramidal geometry with an average W-C distance of 2.169 Å. The spectroscopic and magnetic properties are described.<br /> (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 55
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 27358046
- Full Text :
- https://doi.org/10.1002/anie.201602949