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Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2016 May 04; Vol. 45 (18), pp. 7550-4. - Publication Year :
- 2016
-
Abstract
- The Fe(0) species Fe(N2)(dmpe)2 exists in equilibrium with the previously unreported dimer, [Fe(dmpe2)2(μ-N2)]. For the first time these complexes, alongside Fe(N2)(depe)2, are shown unambiguously to produce N2H4 and/or NH3 upon addition of triflic acid; for Fe(N2)(depe)2 this represents one of the highest electron conversion efficiencies for Fe complexes to date.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 45
- Issue :
- 18
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 27075532
- Full Text :
- https://doi.org/10.1039/c6dt00884d