Designed Assembly of Heterometallic Cluster Organic Frameworks Based on Anderson-Type Polyoxometalate Clusters.

Authors :: Li XX
Wang YX
Wang RH
Cui CY
Tian CB
Yang GY
Source :: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2016 May 23; Vol. 55 (22), pp. 6462-6. Date of Electronic Publication: 2016 Apr 09.
Publication Year :: 2016
Abstract: A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson-type polyoxometalate (POM) clusters and transition-metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three-fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson-type POM clusters and cuprous iodide clusters into one cluster organic framework.<br /> (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

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