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Reductive debromination of 1,2-dibromides with anisidines.

Authors :
McGraw KM
Bowler JT
Ly VT
Erden I
Wu W
Source :
Tetrahedron letters [Tetrahedron Lett] 2016 Jan 20; Vol. 57 (3), pp. 285-287.
Publication Year :
2016

Abstract

vic -Dibromides containing the α-bromocarbonyl or α-bromoaromatic moieties were reductively debrominated to furnish alkenes in high yield. o - and m -Anisidines but not p -anisidine were found to be effective debrominating agents. The reductive debrominations were found to be trans -stereospecific.

Details

Language :
English
ISSN :
0040-4039
Volume :
57
Issue :
3
Database :
MEDLINE
Journal :
Tetrahedron letters
Publication Type :
Academic Journal
Accession number :
26951759
Full Text :
https://doi.org/10.1016/j.tetlet.2015.11.106