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Poly-arginine conjugated triarylmethyl radical as intracellular spin label.

Authors :
Driesschaert B
Bobko AA
Eubank TD
Samouilov A
Khramtsov VV
Zweier JL
Source :
Bioorganic & medicinal chemistry letters [Bioorg Med Chem Lett] 2016 Apr 01; Vol. 26 (7), pp. 1742-4. Date of Electronic Publication: 2016 Feb 19.
Publication Year :
2016

Abstract

Stable triarylmethyl radicals are ideal spin labels used for biomedical electron paramagnetic resonance applications. Previously reported structures exhibit polar charged functions for water solubilization preventing them from crossing the cell membrane. We report the synthesis of a triarylmethyl radical conjugated to poly-arginine peptide allowing intracellular delivery of the paramagnetic label.<br /> (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Details

Language :
English
ISSN :
1464-3405
Volume :
26
Issue :
7
Database :
MEDLINE
Journal :
Bioorganic & medicinal chemistry letters
Publication Type :
Academic Journal
Accession number :
26923698
Full Text :
https://doi.org/10.1016/j.bmcl.2016.02.048