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Alternating chiral selectivity of aldol reactions under the confined space of mesoporous silica.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Dec 14; Vol. 51 (96), pp. 17116-9. - Publication Year :
- 2015
-
Abstract
- The chiral selectivities were altered and high diastereo- and enantio-selectivities of the products were obtained in water medium without adding acid co-catalysts when a primary-tertiary diamine catalyst was immobilized on mesoporous SBA-15 to form a recyclable catalyst for the direct asymmetric aldol reaction of cyclohexanone with p-nitrobenzaldehyde.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 51
- Issue :
- 96
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 26451656
- Full Text :
- https://doi.org/10.1039/c5cc07255g