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Amphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in water.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2016 Jan 11; Vol. 52 (3), pp. 457-60. Date of Electronic Publication: 2015 Oct 07. - Publication Year :
- 2016
-
Abstract
- An amphiphilic polymeric micelle is utilized as a microreactor to load a hydrophobic [FeFe]-hydrogenase mimic in water. The local concentration enhancement and strong interaction between the mimic and the photosensitizer as well as the water-mediated fast proton migration caused by the microreactor improve photocatalytic hydrogen production remarkably in water.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 52
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 26442776
- Full Text :
- https://doi.org/10.1039/c5cc07499a