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Ruthenium indenylidene "1(st) generation" olefin metathesis catalysts containing triisopropyl phosphite.
- Source :
-
Beilstein journal of organic chemistry [Beilstein J Org Chem] 2015 Sep 01; Vol. 11, pp. 1520-7. Date of Electronic Publication: 2015 Sep 01 (Print Publication: 2015). - Publication Year :
- 2015
-
Abstract
- The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords "1(st) generation" cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.
Details
- Language :
- English
- ISSN :
- 1860-5397
- Volume :
- 11
- Database :
- MEDLINE
- Journal :
- Beilstein journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26425210
- Full Text :
- https://doi.org/10.3762/bjoc.11.166