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[Removal Characteristics of Elemental Mercury by Mn-Ce/molecular Sieve].

Authors :
Tan ZQ
Niu GP
Chen XW
An Z
Source :
Huan jing ke xue= Huanjing kexue [Huan Jing Ke Xue] 2015 Jun; Vol. 36 (6), pp. 1983-8.
Publication Year :
2015

Abstract

The impregnation method was used to support molecular sieve with active manganese and cerium components to obtain a composite molecular sieve catalyst. The mercury removal performance of the catalyst was studied with a bench-scale setup. XPS analysis was used to characterize the sample before and after the modification in order to study the changes in the active components of the catalyst prepared. The results showed that the catalyst carrying manganese and cerium components had higher oxidation ability of elemental mercury in the temperature range of 300 degrees C - 450 degrees C, especially at 450 degrees C, the oxidation efficiency of elemental mercury was kept above 80%. The catalyst had more functional groups that were conducive to the oxidation of elemental mercury, and the mercury removal mainly depended on the chemical adsorption. The SO2 and NO in flue gas could inhibit the oxidation of elemental mercury to certain extent.

Details

Language :
Chinese
ISSN :
0250-3301
Volume :
36
Issue :
6
Database :
MEDLINE
Journal :
Huan jing ke xue= Huanjing kexue
Publication Type :
Academic Journal
Accession number :
26387298