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Highly regioselective para-methylthiolation/bridging methylenation of arylamines promoted by NH4I.
- Source :
-
Organic & biomolecular chemistry [Org Biomol Chem] 2015 Oct 14; Vol. 13 (38), pp. 9742-5. - Publication Year :
- 2015
-
Abstract
- Aryl methyl thioethers and methylene-bridged arylamines were synthesized via highly regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as the methylthio or methylene source in the presence of NH4I under metal-free conditions. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields.
Details
- Language :
- English
- ISSN :
- 1477-0539
- Volume :
- 13
- Issue :
- 38
- Database :
- MEDLINE
- Journal :
- Organic & biomolecular chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26337143
- Full Text :
- https://doi.org/10.1039/c5ob01679g