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Photoinduced Charge Separation in a Donor-Spacer-Acceptor Dyad with N-Annulated Perylene Donor and Methylviologen Acceptor.
- Source :
-
Chemphyschem : a European journal of chemical physics and physical chemistry [Chemphyschem] 2015 Oct 26; Vol. 16 (15), pp. 3147-50. Date of Electronic Publication: 2015 Aug 31. - Publication Year :
- 2015
-
Abstract
- The first donor-acceptor species in which a strongly emissive N-annulated perylene dye is connected to a methylviologen electron acceptor unit via its macrocyclic nitrogen atom, is prepared by a stepwise, modular procedure. The absorption spectra, redox behavior, spectroelectrochemistry and photophysical properties of this dyad and of its model species are investigated, also by pump-probe fs transient absorption spectroscopy. Photoinduced oxidative electron transfer from the excited state of the dyad, centered on the N-annulated perylene subunit, to the appended methyviologen electron acceptor takes place in a few ps. The charge-separated species recombines in 19 ps. Our results indicate that N-annulated perylene can be connected to functional units by taking advantage of the macrocyclic nitrogen, an option never used until now, without losing their properties, so opening the way to new designing approaches.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1439-7641
- Volume :
- 16
- Issue :
- 15
- Database :
- MEDLINE
- Journal :
- Chemphyschem : a European journal of chemical physics and physical chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26331881
- Full Text :
- https://doi.org/10.1002/cphc.201500615