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A [2 + 3] Reductive Cyclodimerization of Quinoline by SmI2.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2015 Sep 04; Vol. 80 (17), pp. 8929-32. Date of Electronic Publication: 2015 Aug 26. - Publication Year :
- 2015
-
Abstract
- Pyridine and its derivatives are rather difficult to reduce, and the products often undergo a very fast reoxidation to regain aromaticity. The reduction of quinoline by SmI2 results in an instantaneous [2 + 3] cyclization reaction, forming a bridged seven-membered ring within a polycyclic system.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 80
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26266694
- Full Text :
- https://doi.org/10.1021/acs.joc.5b01572