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Gold dithiolene complexes: easy access to 2-alkylthio-thiazoledithiolate complexes.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Sep 21; Vol. 44 (35), pp. 15683-9. Date of Electronic Publication: 2015 Aug 07. - Publication Year :
- 2015
-
Abstract
- In the presence of MeI or EtI, N-tert-butyl-1,3-thiazoline-2-thione derivatives undergo a transformation to 2-alkylthio-thiazoledithiolate pro-ligands with elimination of the tert-butyl substituent. The corresponding Au(III) dithiolene complexes [Au(RS-tzdt)2](-) (R = Me, Et) oxidize readily to the neutral radical species, such as the semi-conducting [Au(EtS-tzdt)2]˙, which organizes into dimers in the solid state.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 44
- Issue :
- 35
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 26252248
- Full Text :
- https://doi.org/10.1039/c5dt02534f