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Crystal structure of trans-dihydrido-bis[tris-(di-methyl-amino)-phosphane-κP]platinum(II).

Authors :
Downs EL
Zakharov LN
Tyler DR
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Mar 14; Vol. 71 (Pt 4), pp. m83-4. Date of Electronic Publication: 2015 Mar 14 (Print Publication: 2015).
Publication Year :
2015

Abstract

The mol-ecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the Pt(II) atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt(II) atom sits on an inversion center and thus the asymmetric unit contains only half the mol-ecule. The Pt-P and Pt-H distances are 2.2574 (10) and 1.49 (7) Å, respectively.

Details

Language :
English
ISSN :
2056-9890
Volume :
71
Issue :
Pt 4
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
26029413
Full Text :
https://doi.org/10.1107/S2056989015004351