Crystal structure of bis-[1,3-bis-(di-phenyl-phosphan-yl)propane-κ(2) P,P']platinum(II) dichloride chloro-form penta-solvate.

Authors :: Anderson BG
Hoyte SA
Spencer JL
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Jan 28; Vol. 71 (Pt 2), pp. m37. Date of Electronic Publication: 2015 Jan 28 (Print Publication: 2015).
Publication Year :: 2015
Abstract: In the title compound, [Pt{Ph2P(CH2)3PPh2}2]Cl2·5CHCl3, the Pt(II) cations, located on a centre of inversion, is coordinated by two chelating diphosphane ligands in a geometry which is close to square-planar. The chelate rings adopt a chair conformation. The Pt(II) cations are arranged in layers separated by Cl(-) anions as well as CHCl3 solvent mol-ecules. While this complex has been reported previously [Anderson et al. (1983 ▶). Inorg. Chim. Acta, 76, L251-L252], this is the first time a structure has been determined.

Language :: English
ISSN :: 2056-9890
Volume :: 71
Issue :: Pt 2
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 25878844
Full Text :: https://doi.org/10.1107/S205698901500136X

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