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Crystal structure of (Z)-3-(4-meth-oxy-benzyl-idene)-2,3-di-hydro-benzo[b][1,4]thia-zepin-4(5H)-one.

Authors :
Vinayagam V
Mohan Raj J
Murugavel S
Selvakumar R
Bakthadoss M
Source :
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Jan 01; Vol. 71 (Pt 1), pp. o21-2. Date of Electronic Publication: 2015 Jan 01 (Print Publication: 2015).
Publication Year :
2015

Abstract

In the title compound, C17H15NO2S, the two C atoms linking the S and carbonyl C atoms of the seven-membered thia-zepine ring are disordered over two sites, with occupancies of 0.511 (4) and 0.489 (4); both disorder components adopt distorted twist-boat conformations. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds link inverted-related mol-ecules into dimers, incorporating R 1 (2)(6) and R 2 (2)(8) ring motifs; the acceptor carbonyl O atom is bifurcated. These dimers are further linked by C-H⋯O hydrogen bonds, forming supra-molecular tapes running along the a axis.

Details

Language :
English
ISSN :
2056-9890
Volume :
71
Issue :
Pt 1
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Crystallographic communications
Publication Type :
Academic Journal
Accession number :
25705485
Full Text :
https://doi.org/10.1107/S2056989014026267