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Palladium(II)-catalysed ortho-arylation of N-benzylpiperidines.

Authors :
Tan PW
Haughey M
Dixon DJ
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Mar 14; Vol. 51 (21), pp. 4406-9.
Publication Year :
2015

Abstract

Pd(II)-catalysed ortho-arylation of benzylic heterocycles with arylboronic acid pinacol esters (Ar-BPin) via directed C-H bond activation to generate the desired biaryl products is reported. This methodology is efficient and applicable to a wide range of functionalised Ar-BPin and benzylic heterocycles, allowing the direct synthesis of important biaryl motifs in modest to good yield.

Details

Language :
English
ISSN :
1364-548X
Volume :
51
Issue :
21
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
25679348
Full Text :
https://doi.org/10.1039/c5cc00410a