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Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Mar 14; Vol. 44 (10), pp. 4759-64. - Publication Year :
- 2015
-
Abstract
- A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature. No additional oxidizing agent, base, or phosphine ligands are required.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 44
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 25665712
- Full Text :
- https://doi.org/10.1039/c4dt03492a