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Aggregation behavior and total miscibility of fluorinated ionic liquids in water.
- Source :
-
Langmuir : the ACS journal of surfaces and colloids [Langmuir] 2015 Feb 03; Vol. 31 (4), pp. 1283-95. Date of Electronic Publication: 2015 Jan 22. - Publication Year :
- 2015
-
Abstract
- In this work, novel and nontoxic fluorinated ionic liquids (FILs) that are totally miscible in water and could be used in biological applications, where fluorocarbon compounds present a handicap because their aqueous solubility (water and biological fluids) is in most cases too low, have been investigated. The self-aggregation behavior of perfluorosulfonate-functionalized ionic liquids in aqueous solutions has been characterized using conductometric titration, isothermal titration calorimetry (ITC), surface tension measurements, dynamic light scattering (DLS), viscosity and density measurements, and transmission electron microscopy (TEM). Aggregation and interfacial parameters have been computed by conductimetry, calorimetry, and surface tension measurements in order to study various thermodynamic and surface properties that demonstrate that the aggregation process is entropy-driven and that the aggregation process is less spontaneous than the adsorption process. The novel perfluorosulfonate-functionalized ILs studied in this work show improved surface activity and aggregation behavior, forming distinct self-assembled structures.
Details
- Language :
- English
- ISSN :
- 1520-5827
- Volume :
- 31
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- Langmuir : the ACS journal of surfaces and colloids
- Publication Type :
- Academic Journal
- Accession number :
- 25580898
- Full Text :
- https://doi.org/10.1021/la503961h