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Formation of a zwitterionic boronium species from the reaction of a stable carbenoid with borane: CO2 reduction.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Feb 07; Vol. 51 (11), pp. 2107-10. Date of Electronic Publication: 2014 Dec 23. - Publication Year :
- 2015
-
Abstract
- The treatment of Li2C(PPh2NMes)2 (1, Mes = 2,4,6-Me3C6H2) with hexachloroethane yielded the corresponding carbenoid 2 in good yields. The reactivity of 2 was studied with BH3·SMe2 to give a zwitterionic boronium species 4, also a stable carbenoid. Both carbenoid species were found to be excellent catalysts for the CO2 reduction by BH3·SMe2.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 51
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 25536124
- Full Text :
- https://doi.org/10.1039/c4cc09239b