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Cobalt catalyst with a proton-responsive ligand for water oxidation.

Authors :
Siewert I
Gałęzowska J
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2015 Feb 09; Vol. 21 (7), pp. 2780-4. Date of Electronic Publication: 2014 Dec 18.
Publication Year :
2015

Abstract

Herein, we report the synthesis, the thermochemical data, and the catalytic reactivity of a new mononuclear cobalt complex, which has four NH protons in the ligand sphere. The combination of the redox-active metal ion and NH units enabled the coupling of proton and electron-transfer steps, which we exploited in the electrocatalytic water oxidation.<br /> (© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
21
Issue :
7
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
25524133
Full Text :
https://doi.org/10.1002/chem.201405020