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Bifunctional photoacids: remote protonation affecting chemical reactivity.
- Source :
-
The journal of physical chemistry. B [J Phys Chem B] 2015 Feb 12; Vol. 119 (6), pp. 2690-701. Date of Electronic Publication: 2014 Nov 19. - Publication Year :
- 2015
-
Abstract
- Reversible protonation (deprotonation) of a side-group is a useful and convenient way to affect the reactivity of large organic and biological molecules. We use bifunctional photoacids to demonstrate how the protonation state of a basic side-group (COO(-)) controls the reactivity of the main acidic group of the photoacid (OH), both in the ground and the electronic excited state of 6-carboxy derivatives of 2-naphthol.
Details
- Language :
- English
- ISSN :
- 1520-5207
- Volume :
- 119
- Issue :
- 6
- Database :
- MEDLINE
- Journal :
- The journal of physical chemistry. B
- Publication Type :
- Academic Journal
- Accession number :
- 25369117
- Full Text :
- https://doi.org/10.1021/jp509104x