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Synthesis and reactivity of new aminophenolate complexes of nickel.
- Source :
-
Molecules (Basel, Switzerland) [Molecules] 2014 Sep 02; Vol. 19 (9), pp. 13603-13. Date of Electronic Publication: 2014 Sep 02. - Publication Year :
- 2014
-
Abstract
- New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
Details
- Language :
- English
- ISSN :
- 1420-3049
- Volume :
- 19
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Molecules (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 25185067
- Full Text :
- https://doi.org/10.3390/molecules190913603