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Diastereoselective synthesis of fused lactone-pyrrolidinones; application to a formal synthesis of (-)-salinosporamide A.

Authors :
Logan AW
Sprague SJ
Foster RW
Marx LB
Garzya V
Hallside MS
Thompson AL
Burton JW
Source :
Organic letters [Org Lett] 2014 Aug 15; Vol. 16 (16), pp. 4078-81. Date of Electronic Publication: 2014 Jul 28.
Publication Year :
2014

Abstract

A mild, diastereoselective synthesis of fused lactone-pyrrolidinones using an oxidative radical cyclization is reported. The methodology is demonstrated in a formal synthesis of (-)-salinosporamide A.

Details

Language :
English
ISSN :
1523-7052
Volume :
16
Issue :
16
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
25068416
Full Text :
https://doi.org/10.1021/ol501662t