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Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones.
- Source :
-
Organic & biomolecular chemistry [Org Biomol Chem] 2014 Sep 14; Vol. 12 (34), pp. 6672-6. - Publication Year :
- 2014
-
Abstract
- The iridium(I) hydroxide complex [Ir(OH)(COD)(I(i)Pr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1-1.5 h) with microwave heating, in the absence of additives.
Details
- Language :
- English
- ISSN :
- 1477-0539
- Volume :
- 12
- Issue :
- 34
- Database :
- MEDLINE
- Journal :
- Organic & biomolecular chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 25031155
- Full Text :
- https://doi.org/10.1039/c4ob01428f