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Nonanebis(peroxoic acid): a stable peracid for oxidative bromination of aminoanthracene-9,10-dione.

Authors :
Patil VV
Shankarling GS
Source :
Beilstein journal of organic chemistry [Beilstein J Org Chem] 2014 Apr 24; Vol. 10, pp. 921-8. Date of Electronic Publication: 2014 Apr 24 (Print Publication: 2014).
Publication Year :
2014

Abstract

A new protocol for the oxidative bromination of aminoanthracene-9,10-dione, which is highly deactivated towards the electrophilic substitution is investigated. The peracid, nonanebis(peroxoic acid), possesses advantages such as better stability at room temperature, it is easy to prepare and non-shock sensitiv as compared to the conventional peracids. The present protocol has a broad scope for the bromination of various substituted and unsubstituted aminoanthracene-9,10-diones.

Details

Language :
English
ISSN :
1860-5397
Volume :
10
Database :
MEDLINE
Journal :
Beilstein journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
24991241
Full Text :
https://doi.org/10.3762/bjoc.10.90