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Aromatic nucleophilic substitution (S(N)Ar) of meso-nitroporphyrin with azide and amines as an alternative metal catalyst free synthetic approach to obtain meso-N-substituted porphyrins.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2014 Jul 18; Vol. 79 (14), pp. 6424-34. Date of Electronic Publication: 2014 Jul 02. - Publication Year :
- 2014
-
Abstract
- Aromatic nucleophilic substitution reaction of the nitro group of meso-nitroporphyrins with azide and various amines was achieved and represents an alternative procedure to C-N coupling reactions usually needed to obtain such meso-N-substituted porphyrins in good yields.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 79
- Issue :
- 14
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 24960068
- Full Text :
- https://doi.org/10.1021/jo5005586