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Silver-mediated radical cyclization: construction of Δ(2)-isoxazolines from α-halo ketoximes and 1,3-dicarbonyl compounds.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Jul 04; Vol. 50 (52), pp. 6906-8. - Publication Year :
- 2014
-
Abstract
- A novel route to Δ(2)-isoxazolines is presented via silver-mediated radical cyclization of α-halo ketoximes with 1,3-dicarbonyl compounds. This method is performed using a radical strategy, and represents a new example of silver-initiated generation of oxime radicals for the formation of the C(sp(3))-O bonds.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 50
- Issue :
- 52
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 24840629
- Full Text :
- https://doi.org/10.1039/c4cc02084g