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Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 May 30; Vol. 50 (42), pp. 5629-32. - Publication Year :
- 2014
-
Abstract
- The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)5[Mn(II)2Cr(III)3(ox)9]·10H2O, with an unusual Mn(II)/Cr(III) ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 50
- Issue :
- 42
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 24728206
- Full Text :
- https://doi.org/10.1039/c4cc00607k