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Axially chiral BODIPYs.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 May 11; Vol. 50 (36), pp. 4714-6. - Publication Year :
- 2014
-
Abstract
- The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 50
- Issue :
- 36
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 24676233
- Full Text :
- https://doi.org/10.1039/c4cc00851k