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High-turnover visible-light photoreduction of CO2 by a Re(I) complex stabilized on dye-sensitized TiO2.

Authors :
Ha EG
Chang JA
Byun SM
Pac C
Jang DM
Park J
Kang SO
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 May 04; Vol. 50 (34), pp. 4462-4. Date of Electronic Publication: 2014 Mar 21.
Publication Year :
2014

Abstract

Hybrid systems prepared by fixing a Re(i) complex and a dye on three types of TiO2 nanoparticles in two different ways commonly revealed persistent photocatalysis of the CO2 reduction to CO with no levelling-off tendency under visible-light irradiation in DMF, giving a turnover number of ≥435.

Details

Language :
English
ISSN :
1364-548X
Volume :
50
Issue :
34
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
24660220
Full Text :
https://doi.org/10.1039/c3cc49744e