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Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts.

Authors :
Hussein L
Purkait N
Biyikal M
Tausch E
Roesky PW
Blechert S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Apr 14; Vol. 50 (29), pp. 3862-4.
Publication Year :
2014

Abstract

New bimetallic Zn/Zr salen-type systems were employed as catalysts in the asymmetric intramolecular hydroamination reaction. High enantioselectivity for the formation of piperidines of up to 98% ee were observed.

Details

Language :
English
ISSN :
1364-548X
Volume :
50
Issue :
29
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
24592399
Full Text :
https://doi.org/10.1039/c3cc48874h