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Strong electron-donating metalla-N-heterocyclic carbenes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Feb 28; Vol. 50 (17), pp. 2129-32. Date of Electronic Publication: 2014 Jan 14. - Publication Year :
- 2014
-
Abstract
- By choosing the appropriate coupling reactions an isocyanide ligand in complex [Fe(Cp)(CO)(CNxylyl)2](+) is transformed into either a conventional NHC or into a metalla-N-heterocyclic carbene (MNHC), with the stretching frequencies of the CO and CNR ligands attached to the iron center demonstrating the stronger electron-donating ability of the metal-containing carbenes.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 50
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 24419097
- Full Text :
- https://doi.org/10.1039/c3cc47987k