Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple 'pseudo-fluid' model for a ball milling reaction.

Authors :: Ma X
Yuan W
Bell SE
James SL
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Feb 14; Vol. 50 (13), pp. 1585-7.
Publication Year :: 2014
Abstract: Quantitative monitoring of a mechanochemical reaction by Raman spectroscopy leads to a surprisingly straightforward second-order kinetic model in which the rate is determined simply by the frequency of reactive collisions between reactant particles.

Subjects :: Kinetics
Mechanical Phenomena
Models, Chemical
Spectrum Analysis, Raman methods

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