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Design of aromatic heteropolycyclics containing borole frameworks.

Authors :
Tai TB
Huong VT
Nguyen MT
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Dec 21; Vol. 49 (98), pp. 11548-50.
Publication Year :
2013

Abstract

The heteropolycyclic compounds containing borole units were theoretically designed. The presence of electron deficient boron atoms results in full electron delocalization and remarkably affects their aromaticity. While molecules 1 and 2a exhibit antiaromaticity for inner rings and non-aromaticity for outer rings, 2b and 2c are completely aromatic.

Details

Language :
English
ISSN :
1364-548X
Volume :
49
Issue :
98
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
24178129
Full Text :
https://doi.org/10.1039/c3cc47573e