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Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2014 Jan 07; Vol. 43 (1), pp. 34-7. - Publication Year :
- 2014
-
Abstract
- A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 43
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 24162511
- Full Text :
- https://doi.org/10.1039/c3dt52762j