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On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Dec 07; Vol. 49 (94), pp. 11083-5. - Publication Year :
- 2013
-
Abstract
- Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C4mim] [Ac] in the liquid phase. The formation of [C4mim] CO2, [C4mim] COS, CH3COS(-) and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not observed in the CO2-[C4mim] [Ac] reaction.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 49
- Issue :
- 94
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 24141427
- Full Text :
- https://doi.org/10.1039/c3cc46038j