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Tetraammine(carbonato-κ(2) O,O')cobalt(III) perchlorate.

Authors :
Mohan SC
Jenniefer SJ
Muthiah PT
Jothivenkatachalam K
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Jul 06; Vol. 69 (Pt 8), pp. i45-i46. Date of Electronic Publication: 2013 Jul 06 (Print Publication: 2013).
Publication Year :
2013

Abstract

In the title complex, [Co(CO3)(NH3)4]ClO4, both the cation and anion lie on a mirror plane. The Co(III) ion is coordinated by two NH3 ligands and a chelating carbonato ligand in the equatorial sites and by two NH3 groups in the axial sites, forming a distorted octa-hedral geometry. In the crystal, N-H⋯O hydrogen bonds connect the anions and cations, forming a three-dimensional network.

Details

Language :
English
ISSN :
1600-5368
Volume :
69
Issue :
Pt 8
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
24109252
Full Text :
https://doi.org/10.1107/S1600536813018187