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Unprecedented activation and CO2 capture properties of an elastic single-molecule trap.

Authors :
Wriedt M
Sculley JP
Verdegaal WM
Yakovenko AA
Zhou HC
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Oct 25; Vol. 49 (83), pp. 9612-4.
Publication Year :
2013

Abstract

The activation and CO2 capture properties of a microporous metal-organic framework with elastic single-molecule traps were systematically investigated. This material shows a unique low-energy gas-purge activation capability, high CO2 adsorption selectivities over various gases and optimized working capacities per energy of 2.9 mmol kJ(-1) at 128 °C.

Details

Language :
English
ISSN :
1364-548X
Volume :
49
Issue :
83
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
24022838
Full Text :
https://doi.org/10.1039/c3cc45866k