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Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Oct 18; Vol. 49 (81), pp. 9263-5. - Publication Year :
- 2013
-
Abstract
- The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as an electrophilic fluorinating reagent for the first time to monofluorinate 1,3-ketoesters and difluorinate 1,3-diketones in good isolated yields.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 49
- Issue :
- 81
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 23998186
- Full Text :
- https://doi.org/10.1039/c3cc44792h