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Refining the interpretation of near-infrared band shapes in a polyynediyl molecular wire.

Authors :
Parthey M
Gluyas JB
Schauer PA
Yufit DS
Howard JA
Kaupp M
Low PJ
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2013 Jul 22; Vol. 19 (30), pp. 9780-4. Date of Electronic Publication: 2013 Jun 12.
Publication Year :
2013

Abstract

Spinning to improve (band) shape: A blend of theoretical and experimental work demonstrates that the rotational conformation of mixed-valence complexes influences the low-energy (NIR) transitions in such molecules. Interpretations of the NIR band shapes are presented.<br /> (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Details

Language :
English
ISSN :
1521-3765
Volume :
19
Issue :
30
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
23852956
Full Text :
https://doi.org/10.1002/chem.201301747