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1-(Prop-2-en-1-yl)-3-{[3-(pyridin-4-yl)-4,5-di-hydro-isoxazol-5-yl]meth-yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione.

Authors :
Afrakssou Z
Kandri Rodia Y
Capet F
Essassi el M
Rolando C
El Ammari L
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 May 22; Vol. 69 (Pt 6), pp. o945-6. Date of Electronic Publication: 2013 May 22 (Print Publication: 2013).
Publication Year :
2013

Abstract

The fused five- and three six-membered rings of the anthra[1,2-d]imidazole-trione part of the title compound, C27H20N4O4, show two different substituents at the imidazole N atoms, viz. an allyl group and a [3-(pyridin-4-yl)-4,5-di-hydro-isoxazol-5-yl]methyl group. The fused-ring system is approximately planar [r.m.s. deviation = 0.232 (2) Å], but is slightly buckled along the common edge of the two pairs of adjacent rings, with a dihedral angle between them of 11.17 (6)°. The isoxazole ring makes dihedral angles of 27.2 (2) and 12.7 (2)° with the imidazole and pyridine rings, respectively. Weak C-H⋯O and C-H⋯N hydrogen bonds ensure the cohesion of the crystal structure, forming a three-dimensional network.

Details

Language :
English
ISSN :
1600-5368
Volume :
69
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
23795108
Full Text :
https://doi.org/10.1107/S160053681301369X