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3-(Ammonio-methyl)-pyridinium bis-(perchlorate).

Authors :
Bayar I
Kefi R
Sidonio Pereira da Silva P
Ramos Silva M
Ben Nasr C
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 May 11; Vol. 69 (Pt 6), pp. o843. Date of Electronic Publication: 2013 May 11 (Print Publication: 2013).
Publication Year :
2013

Abstract

In the title molecular salt, C6H10N2 (2+)·2ClO4 (-), the Cl-O bond lengths [anion 1: 1.369 (3)-1.415 (3); anion 2: 1.420 (2)-1.441 (2) Å] and the O-Cl-O angles [anion 1: 105.4 (2)-111.8 (4); anion 2: 107.8 (1)-110.3 (1)°] indicate a slight distortion of the perchlorate anions from regular tetra-hedral symmetry. In the crystal, the components are linked into columns along the a-axis direction via N-H⋯O and C-H⋯O hydrogen bonds, with stacks of the organic mol-ecules being surrounded by stacks of perchlorate anions.

Details

Language :
English
ISSN :
1600-5368
Volume :
69
Issue :
Pt 6
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
23795030
Full Text :
https://doi.org/10.1107/S1600536813012038