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Why silver deposition is so fast: solving the enigma of metal deposition.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2013 Jul 22; Vol. 52 (30), pp. 7883-5. Date of Electronic Publication: 2013 Jun 20. - Publication Year :
- 2013
-
Abstract
- A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag(+) ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag(+) ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction.<br /> (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 52
- Issue :
- 30
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 23788512
- Full Text :
- https://doi.org/10.1002/anie.201301998