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Bis[2,4-di-bromo-6-(N-{4-[(E)-1-(benzyl-oxy-imino)-eth-yl]phen-yl}carboximido-yl)phenolato]copper(II).

Authors :
Li XB
Li XJ
Meng WS
Zhang YJ
Li G
Source :
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Apr 13; Vol. 69 (Pt 5), pp. m267. Date of Electronic Publication: 2013 Apr 13 (Print Publication: 2013).
Publication Year :
2013

Abstract

In the title complex, [Cu(C22H17Br2N2O2)2], the Cu(II) ion is four-coordinated in a trans-CuN2O2 square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the mol-ecules is controlled by C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.568 (3), 3.678 (2), 3.717 (3) and 3.799 (2) Å] and weak Br⋯Br halogen bonds [3.508 (4) Å], linking the mol-ecules into an infinite three-dimensional supra-molecular network.

Details

Language :
English
ISSN :
1600-5368
Volume :
69
Issue :
Pt 5
Database :
MEDLINE
Journal :
Acta crystallographica. Section E, Structure reports online
Publication Type :
Academic Journal
Accession number :
23723774
Full Text :
https://doi.org/10.1107/S1600536813009847