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Architectural spiroligomers designed for binuclear metal complex templating.

Authors :
Vaddypally S
Xu C
Zhao S
Fan Y
Schafmeister CE
Zdilla MJ
Source :
Inorganic chemistry [Inorg Chem] 2013 Jun 03; Vol. 52 (11), pp. 6457-63. Date of Electronic Publication: 2013 May 13.
Publication Year :
2013

Abstract

The first structurally, spectroscopically, and electronically characterized metal-spiroligomer complexes are reported. The binuclear [M2L2](4+) ions (M = Mn, Zn) are macrocyclic "squares" and are characterized by X-ray diffraction, (1)H and (13)C NMR, electronic absorption, emission, and mass spectroscopies. The manganese complex contains two spin-independent Mn(II) ions and is additionally characterized using EPR and CD spectroscopies and CV.

Details

Language :
English
ISSN :
1520-510X
Volume :
52
Issue :
11
Database :
MEDLINE
Journal :
Inorganic chemistry
Publication Type :
Academic Journal
Accession number :
23668771
Full Text :
https://doi.org/10.1021/ic4003498