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Postsynthesis modification of a porous coordination polymer by LiCl To enhance H+ transport.
- Source :
-
Journal of the American Chemical Society [J Am Chem Soc] 2013 Mar 27; Vol. 135 (12), pp. 4612-5. Date of Electronic Publication: 2013 Mar 18. - Publication Year :
- 2013
-
Abstract
- A Ca(2+) porous coordination polymer with 1D channels was functionalized by the postsynthesis addition of LiCl to enhance the H(+) conductivity. The compound showed over 10(-2) S cm(-1) at 25 °C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H(+) conductivity was achieved by the support of Li(+) ion movements in the channel.
Details
- Language :
- English
- ISSN :
- 1520-5126
- Volume :
- 135
- Issue :
- 12
- Database :
- MEDLINE
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 23485151
- Full Text :
- https://doi.org/10.1021/ja3122872