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Preparation and X-ray structural study of 1-arylbenziodoxolones.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2013 Apr 19; Vol. 78 (8), pp. 3767-73. Date of Electronic Publication: 2013 Mar 21. - Publication Year :
- 2013
-
Abstract
- Various 1-arylbenziodoxolones can be conveniently prepared from 2-iodobenzoic acid and arenes by a one-pot procedure using Oxone (2KHSO5·KHSO4·K2SO4) as an inexpensive and environmentally safe oxidant. This procedure is also applicable for the synthesis of the 7-methylbenziodoxolone ring system using 2-iodo-3-methylbenzoic acid as starting compound. Structures of four 1-arylbenziodoxolone derivatives were established by single-crystal X-ray diffraction analysis. An enhanced reactivity of 1-aryl-7-methylbenziodoxolones toward nucleophiles compared to unsubstituted 1-arylbenziodoxolones has been found.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 78
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 23480389
- Full Text :
- https://doi.org/10.1021/jo400212u