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Crystallographic and solution NMR structural analyses of four hexacoordinated gallium(III) complexes based on ligands derived from 6-amino-perhydro-1,4-diazepine.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2013 Jun 14; Vol. 42 (22), pp. 8001-8. Date of Electronic Publication: 2013 Mar 07. - Publication Year :
- 2013
-
Abstract
- The crystal structures are reported of four gallium(III) complexes based on two pairs of 6-substituted-6-amino-perhydro-1,4-diazepine ligands, together with a study of their solution structures examined by (1)H and (71)Ga NMR spectroscopy. In each case, the ligand adopts a twisted chair conformation that creates a facial array of the three ligand nitrogen atoms. The coordination geometry about each gallium(III) ion is a slightly distorted octahedron, with the 6-phenyl series being slightly more distorted than the 6-methyl analogues. Pulsed NMR experiments allow solution NMR structures to be assessed, revealing good agreement with the solid-state structures.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 42
- Issue :
- 22
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 23471161
- Full Text :
- https://doi.org/10.1039/c3dt50287b