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N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation.

Authors :
Gatineau D
Zhao Q
Curran DP
Malacria M
Lacôte E
Fensterbank L
Goddard JP
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2013 May 28; Vol. 42 (20), pp. 7458-62.
Publication Year :
2013

Abstract

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

Details

Language :
English
ISSN :
1477-9234
Volume :
42
Issue :
20
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
23459715
Full Text :
https://doi.org/10.1039/c3dt32983f